The “Friends” star and her A-list beau first met in 1994.

However, it wasn’t until four years later that they began dating.

The two connected followingPitt’s split with Gwyneth Paltrowand Aniston’s breakup with actor Tate Donovan.

Brad Pitt poses for a photo

In 1999, Aniston and Pitt announced their engagement and by the summer of 2000 they tied the knot.

The couple seemed to have it all.

Pitt even guest-starred on an episode of “Friends” in 2001.

Brad Pitt and Jennifer Aniston at an event

The couple went into business together, launching their own production company called Plan B Entertainment.

Pitt and Jolie got married in 2014, and Aniston later married Justin Theroux.

Both marriages eventually ended in divorce.

Pitt and Aniston at 2020 SAG Awards

“That came after, Larry.

That came after,” he said of his relationship with Jolie.

The two were seen smiling and laughing during their brief public reunion.

“Jen was happy for Brad.

They congratulated each other and that was it,” a sourcetold Peopleafter the event.

The pair even took the roles of love interests.

“And we speak and there’s no oddness at all.

We had fun, and it was for a great cause,” she added.